subject predicate object context
49601 Creator 3d9f5a6838060f791e133fa6e5265b06
49601 Creator ext-33cf10cfb52b1dd4be923fefd53a709e
49601 Creator ext-ccac11ad5f6b5f0927029543df42c0d6
49601 Creator ext-0f879f22ebb482f7ed92ad4534314a9e
49601 Creator ext-8c767aec92bb3cd8ff1956b0df817928
49601 Creator ext-8ea2332bbb42a1ef641643006ab2816e
49601 Creator ext-c6a48dd0480098ca73af56445ba1734d
49601 Creator ext-d32ebdff84eaf2dc251a79c62a19daaf
49601 Date 2017-06-12
49601 Is Part Of repository
49601 Is Part Of p20452322
49601 abstract Tailoring the surface properties by varying the chemistry and roughness could be of interest for self-cleaning applications. We demonstrate the transformation of hydrophobic ZnO Nano rod (NR) array into superhydrophobic nature by changing the local chemical state and without altering the surface roughness by swift heavy ion (SHI) irradiation. The aligned ZnO NR arrays were irradiated using 150 MeV Ag ions with different fluences from 5E10 to 3E12 ions/cm<sup>2</sup>. The observed static water contact angles of ZnO NRs samples were 103° ± 3°, 152° ± 4°,161° ± 3°, 164° ± 2°, 167° ± 2°,154 ± 3° and 151° ± 2° for the pristine, ion fluencies of 1E11, 3E11, 5E11, 7E11, 1E12 and 3E12 ions cm<sup>−2</sup>, respectively. The change in local surface chemistry via formation of surface oxygen related defects due to electronic excitations induced by ion irradiation determine the water dewetting properties. It is found that surface oxygen related defects could be tuned by varying the fluence of the SHIs. Durability tests show that the SHI induced surface oxygen-deficient ZnO NRs have the stable superhydrophobic behavior for more than a year.
49601 authorList authors
49601 status peerReviewed
49601 uri http://data.open.ac.uk/oro/document/627879
49601 uri http://data.open.ac.uk/oro/document/627880
49601 uri http://data.open.ac.uk/oro/document/627881
49601 uri http://data.open.ac.uk/oro/document/627882
49601 uri http://data.open.ac.uk/oro/document/627883
49601 uri http://data.open.ac.uk/oro/document/627884
49601 uri http://data.open.ac.uk/oro/document/627892
49601 uri http://data.open.ac.uk/oro/document/627894
49601 uri http://data.open.ac.uk/oro/document/627895
49601 uri http://data.open.ac.uk/oro/document/627896
49601 uri http://data.open.ac.uk/oro/document/627897
49601 uri http://data.open.ac.uk/oro/document/627898
49601 uri http://data.open.ac.uk/oro/document/662919
49601 uri http://data.open.ac.uk/oro/document/665278
49601 volume 7
49601 type AcademicArticle
49601 type Article
49601 label Shanmugam Ranjith, Kugalur; Raveendran Nivedita, Lalitha; Asokan, Kandasami; Krishnamurthy, Satheesh ; Pandian, Ramanathaswamy; Kamruddin, Mohammed; Kumar Avasthi, Devesh and Rajendra Kumar, Ramasamy Thangavelu (2017). Robust water repellent ZnO nanorod array by Swift Heavy Ion Irradiation: Effect of Electronic Excitation Induced Local Chemical State Modification. Scientific reports, 7, article no. 3251.
49601 label Shanmugam Ranjith, Kugalur; Raveendran Nivedita, Lalitha; Asokan, Kandasami; Krishnamurthy, Satheesh ; Pandian, Ramanathaswamy; Kamruddin, Mohammed; Kumar Avasthi, Devesh and Rajendra Kumar, Ramasamy Thangavelu (2017). Robust water repellent ZnO nanorod array by Swift Heavy Ion Irradiation: Effect of Electronic Excitation Induced Local Chemical State Modification. Scientific reports, 7, article no. 3251.
49601 Title Robust water repellent ZnO nanorod array by Swift Heavy Ion Irradiation: Effect of Electronic Excitation Induced Local Chemical State Modification
49601 in dataset oro