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42123 Creator 974e4843c2192d7cff8913fe9460740b
42123 Creator 9afccdbe975e25965953e777bb4d6a5f
42123 Creator ext-0999e2ed3c0e010b60224fd892db17cd
42123 Creator ext-0f149575c9c16eb37ad8f108517262f1
42123 Creator ext-415c0d572f8b51d5b980bed1c89ea448
42123 Creator ext-49a2c1237f5ea116d98eb5d6522ff2ac
42123 Creator ext-52f9a1bcdc285a6d15009f1b5a2cae50
42123 Creator ext-8cc8bfb24ad7186ad3c2af4c6f5ef5cf
42123 Creator ext-d16832a04b337d7e5773cfac61de6d29
42123 Creator ext-ea80dc8289bdb1adbcc58556278aa586
42123 Creator ext-f6dcfabcf7a606b029e5e6ca69db6198
42123 Date 2014
42123 Is Part Of repository
42123 abstract Wetlands are the largest source of CH<sub>4</sub> to the atmosphere, but emissions measurements are highly uncertain, particularly in the tropics. We examine CH<sub>4</sub> production and transport in a pristine tropical peatland in Borneo. We use the carbon isotopic (stable and radioactive) composition of dissolved CH<sub>4</sub>, DIC and DOC within the peat porewater to identify the source and mechanism of CH<sub>4</sub> production in tropical peat. First, we measure <sup>14</sup>C in all carbon phases to identify the source of CH<sub>4</sub>. In contrast to the peat, which ages with depth to nearly 3000 cal BP, DOC is modern throughout the peat column, to depths of 4.5m. The <sup>14</sup>C content of CH<sub>4</sub> and DIC are nearly identical, and are intermediate between the DOC and peat 14C content. Thus, despite the presence of modern carbon throughout the peat profile, peat decomposition is an important source of CH<sub>4</sub> production. Next, we use the δ<sup>13</sup>C of CH<sub>4</sub> and DIC to identify the mechanism of CH<sub>4</sub> production. Within the peat profile, CH<sub>4</sub> and DIC concentrations increase with depth and DIC becomes increasingly enriched in <sup>13</sup>C. The δ<sup>13</sup>C of CH<sub>4</sub> is relatively uniform with depth, resulting in a δ<sup>13</sup>C fractionation between DIC and CH<sub>4</sub> of 55-70‰ (α<sub>C</sub>CO<sub>2</sub>-CH<sub>4</sub> = 1.06-1.07). This fractionation suggests CO<sub>2</sub> reduction is the dominant pathway for CH<sub>4</sub> production at the site. We find consistent trends with depth across the peatland, attributable to the unique hydrologic behavior of the dome. These trends are similar to those observed in northern peat bogs. Finally, we use information on site hydrology, CH<sub>4</sub> and DIC concentrations, isotopic compositions and fluxes to build a model of CH<sub>4</sub> production and transport. This model allows us to partition CH<sub>4</sub> losses from the peat due to diffusion, tree-mediated transport, and ebullition.
42123 authorList authors
42123 presentedAt ext-2ef34a6047275c1fc4ce06b08d748c34
42123 status nonPeerReviewed
42123 type AcademicArticle
42123 type Article
42123 label Hoyt, Alison; Pangala, Sunitha ; Gandois, Laure; Cobb, Alex; Kai, Fuu-Ming; Xu, Xiaomei; Gauci, Vincent ; Mahmud, Y.; Kamariah, A.; Eri, Jangarun and Harvey, Charles (2014). Methane production and transport in a tropical peatland. In: AGU Fall Meeting, 15-19 Dec 2014, San Francisco, CA, USA.
42123 label Hoyt, Alison; Pangala, Sunitha ; Gandois, Laure; Cobb, Alex; Kai, Fuu-Ming; Xu, Xiaomei; Gauci, Vincent ; Mahmud, Y.; Kamariah, A.; Eri, Jangarun and Harvey, Charles (2014). Methane production and transport in a tropical peatland. In: AGU Fall Meeting, 15-19 Dec 2014, San Francisco, CA, USA.
42123 Title Methane production and transport in a tropical peatland
42123 in dataset oro